carbanide,chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

An samar da hadaddun Chloro na Palladium(II) [(C8H12)(Cl)Pd] ta hanyar daidaitawa tsakanin kwayoyin PdCl4 da kwayoyin trans-(1R,5S)-cycloocta-1,5-diene ta hanyar haɗin gwiwa. Samfurin da aka samar ya ƙunshi ligand dienyl guda ɗaya da aka ɗaure zuwa kowane ɗayan cibiyoyin ƙarfe huɗu ta hanyar haɗin gwiwa na eta. Wannan hadaddun yana da kwanciyar hankali mai zafi saboda ƙarfin intermolecular mai ƙarfi a cikin tsarin. Aikace-aikacensa ya ta'allaka ne musamman a cikin hanyoyin catalytic waɗanda suka haɗa da haɗin gwiwa. Misali, wannan nau'in yana sauƙaƙe samuwar haɗin gwiwa na C-C yayin Suzuki Coupling Reaction wanda ya haɗa da haɗa ƙwayoyin carbon masu haɗaka na sp2 tare ta amfani da boronic acid a matsayin nucleophiles. Sabon haɗin gwiwa da aka samar yana haɓaka halayen kayan da ake amfani da su a cikin na'urorin lantarki don haka yana sa su fi inganci. Bugu da ƙari, wannan mai haɓaka yana samun aikace-aikace a cikin haɗin gwiwa na Sonogashira inda aka haɗa ƙwayoyin sp masu haɗaka ta amfani da alkynes na ƙarshe wanda ke haifar da ƙirƙirar haɗin gwiwa na C-C ta ​​haka yana ƙirƙirar sabbin ƙungiyoyi masu aiki waɗanda ke da yuwuwar amfani a fannoni daban-daban ciki har da haɗa magunguna da kimiyyar kayan aiki.